化学与环境工程学院

College of Chemistry & Environmental Engineering

舒文明

 

舒文明,男,19864月生,讲师,博士,主要从事有机合成方法学的研究工作:即基于自分类反应网络汇聚集成原理设计复杂结构体自组织合成的研究,设计新颖的有机化学反应和多组分反应;通过自序化的反应原理设计获取多个反应中间体,并基于环加成反应作为关键的结合模式选择相关的合成子,原位捕获所生成的活性中间体,进而实现复杂结构体的构造;利用各种捕获子对原位生成的α-重氮酮、苯炔和1,4-烯二酮进行捕获,使之发生环加成反应,合成了一系列的吡唑、噌啉、多取代的萘环、苯环、二氢呋喃[2,3-b]呋喃、以及萘醌并环庚三烯衍生物,为这些化合物的简便高效合成提供新的合成策略和路线。

 

20106月本科毕业于华中师范大学应用化学专业,获理学学士学位;

20166月博士毕业于华中师范大学有机化学专业,获理学博士学位,师从吴安心教授;

20167月至今在长江大学化学与环境工程学院工作。

近年来,先后参与国家自然科学基金2项(2127208521472056),长江大学青年基金1项(2016cqn25),在Chem. Commun., Org. Lett., Chem. Eur. J., J. Org. Chem., Org. Biomol. Chem., Tetrahedron等国外学术刊物上发表SCI论文10余篇。主要承担本科生《现代化学与技术概论》、《有机化学》、《波谱分析》等课程。

E-mail: shuwm@yangtzeu.edu.cn.

 近期代表性论文如下:

(1) Wen-Ming Shu, Kai-Lu Zheng, Jun-Rui Ma, and An-Xin Wu* Transition-Metal-Free Coupling Annulation of Arynes with Ketones and Alkynoates: Assembly of Functionalized Naphthalenes. Org. Lett. 2016, 18, 3762-3765.

(2) Wen-Ming Shu, Jun-Rui Ma, Kai-Lu Zheng, and An-Xin Wu* Multicomponent Coupling Cyclization Access to Cinnolines via in Situ Generated Diazene with Arynes, and α-Bromo Ketones. Org. Lett. 2016, 18, 196-199.

(3) Wen-Ming Shu, Kai-Lu Zheng, Jun-Rui Ma, and An-Xin Wu* Transition-Metal-Free Multicomponent Benzannulation Reactions for the Construction of Polysubstituted Benzene Derivatives. Org. Lett. 2015, 17, 5216-5219.

(4) Wen-Ming Shu, Kai-Lu Zheng, Jun-Rui Ma, Hui-Ying Sun, Mei Wang, and An-Xin Wu* Convenient Access to Polyfunctional Pyrazoles via a Highly Efficient and Regioselective Multicomponent Reaction. Org. Lett. 2015, 17, 1914-1917.

(5) Wen-Ming Shu, Jun-Rui Ma, Yan Yang, and An-Xin Wu* An Efficient Synthesis of Novel Fused Cycloheptatrienes through Mn(II)-Mediated Formal Intermolecular [2+2+2+1] Cycloaddition. Org. Lett. 2014, 16, 1286-1289.

(6) Wen-Ming Shu, Yan Yang, Dong-Xue Zhang, Liu-Ming Wu, Yan-Ping Zhu, Guo-Dong Yin*, and An-Xin Wu* Highly Efficient Synthesis of 3a,6a-Dihydrofuro[2,3-b]furans via a Novel Bicyclization. Org. Lett. 2013, 15, 456-459.

(7) Wen-Ming Shu, Jun-Rui Ma, Kai-Lu Zheng, Hui-Ying Sun, Mei Wang, Yan Yang, and An-Xin Wu* One-pot synthesis of polyfunctional pyrazoles: an easy access to α-diazoketones from arylglyoxal monohydrates and tosylhydrazine. Tetrahedron 2014, 70, 9321-9329.

 (8) Kai-Lu Zheng, Wen-Ming Shu, Jun-Rui Ma, Yan-Dong Wu*, and An-Xin Wu* Acid-Mediated N–H/α,β-C(sp3)–H Trifunctionalization of Pyrrolidine: Intermolecular [3+2] Cycloaddition for the Construction of 2,3-Dihydro-1H-Pyrrolizine Derivatives. Org. Lett., 2016, 18, 3526–3529.

(9) Yan Yang, Wen-Ming Shu, Shang-Bo Yu, Fan Ni, Meng Gao, and An-Xin Wu* Auto-tandem Catalysis: Synthesis of 4H-pyrido[1,2-a]-pyrimidin-4-ones via Copper-catalyzed aza-Michael Addition–aerobic Dehydrogenation–Intramolecular Amidation. Chem. Commun. 2013, 49, 1729-1731.

(10) Jun-Rui Ma, Wen-Ming Shu, Kai-Lu Zheng, Fan Ni, Guo-Dong Yin*, and An-Xin Wu* Efficient Approach to 2-Hydroxy-2,3-Dihydrofuran Derivatives and Its Application for the Synthesis of Novel 4-(1H-pyrazol-4-yl)pyridazines. Org. Biomol. Chem. 2015, 13, 4976-4980.

(11) Yan Yang, Fan Ni, Wen-Ming Shu, and An-Xin Wu* Copper-Catalyzed Domino Synthesis of 2-Imino-1H-imidazol-5(2H)-ones and Quinoxalines Involving C—C Bond Cleavage with a 1,3-Dicarbonyl Unit as a Leaving Group. Chem. Eur. J. 2014, 20, 11776-11782.

(12) Yan Yang, Fan Ni, Wen-Ming Shu, Shang-Bo Yu, Meng Gao, and An-Xin Wu* Synthesis of Tetrasubstituted Unsymmetrical 1,4-Enediones via Copper-Promoted Autotandem Catalysis and Air As the Oxidant. J. Org. Chem. 2013, 78, 5418-5426.

(13) Yan Yang, Meng Gao, Wen-Ming Shu, Liu-Ming Wu, Dong-Xue Zhang, and An-Xin Wu* Synthesis of alpha-iodoketals from methyl ketones via sustainable and orthogonal tandem catalysis. Org. Biomol. Chem. 2013, 11, 1226-1233.